Few‐Layer Antimonene by Liquid‐Phase Exfoliation
نویسندگان
چکیده
We report on a fast and simple method to produce highly stable isopropanol/water (4:1) suspensions of few-layer antimonene by liquid-phase exfoliation of antimony crystals in a process that is assisted by sonication but does not require the addition of any surfactant. This straightforward method generates dispersions of few-layer antimonene suitable for on-surface isolation. Analysis by atomic force microscopy, scanning transmission electron microscopy, and electron energy loss spectroscopy confirmed the formation of high-quality few-layer antimonene nanosheets with large lateral dimensions. These nanolayers are extremely stable under ambient conditions. Their Raman signals are strongly thickness-dependent, which was rationalized by means of density functional theory calculations.
منابع مشابه
Two-dimensional antimonene single crystals grown by van der Waals epitaxy
Unlike the unstable black phosphorous, another two-dimensional group-VA material, antimonene, was recently predicted to exhibit good stability and remarkable physical properties. However, the synthesis of high-quality monolayer or few-layer antimonenes, sparsely reported, has greatly hindered the development of this new field. Here, we report the van der Waals epitaxy growth of few-layer antimo...
متن کاملThe facile fabrication of few-layer graphene and graphite nanosheets by high pressure homogenization.
We demonstrated a facile and efficient approach for the fabrication of few-layer graphene in DMF and graphite nanosheets in water with the assistance of high pressure homogenization. This work provides a physical perspective for understanding the exfoliation of other layered materials in liquid phase exfoliation.
متن کاملPreparation of Few-Layer Bismuth Selenide by Liquid-Phase-Exfoliation and Its Optical Absorption Properties
Bismuth selenide (Bi2Se3), a new topological insulator, has attracted much attention in recent years owing to its relatively simple band structure and large bulk band gap. Compared to bulk, few-layer Bi2Se3 is recently considered as a highly promising material. Here, we use a liquid-phase exfoliation method to prepare few-layer Bi2Se3 in N-methyl-2-pyrrolidone or chitosan acetic solution. The r...
متن کاملProduction of few-layer phosphorene by liquid exfoliation of black phosphorus.
We report the liquid exfoliation of black phosphorus in N-methyl-2-pyrrolidone to form few-layer phosphorene nanosheets.
متن کاملLiquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics
Few-layer black phosphorus (BP) is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of environmental stability severely limits its synthesis and processing. Here we demonstrate that high-quality, few-layer BP nanosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase...
متن کامل